Publication Informations

Synthesis of hybrid polymethacrylate-noble metal (M = Au, Pd) nanoparticles for the growth of metal-oxide semiconductor nanowires
Authors: M. Zervos; M. Demetriou; T. Krasia-Christoforou; A. Othonos; R. P. Turcu
Year: 2012
Research Area: Nanowire synthesis
Type of Publication: Article
Journal Details
Journal: RSC Adv.
Volume: 2
Pages: 4370-4376
Metal-oxide semiconductor nanowires (NWs) such as ZnO{,} [small beta]-Ga2O3 and SnO2 with diameters of tens of nanometres and lengths of many micrometres have been grown using micellar nanohybrids consisting of methacrylate-based diblock copolymers and noble metal nanoparticles (MNPs). Micellar Au and Pd MNPs with diameters as small as 2.3 +/- 0.3 nm were deposited on Si(001) by spin coating or drop casting and metal-oxide NWs were grown by reactive vapor transport. A high yield of [small beta]-Ga2O3 NWs with diameters of approximately 40 nm{,} lengths > 10 [small mu ]m and a monoclinic crystal structure were obtained at 900 [degree]C with the largest MNPs. These exhibited a broad{,} symmetric photoluminescence (PL) spectrum centred at 2.3 eV attributed to defect states situated energetically in the energy band gap of [small beta]-Ga2O3. We find that a reduction in the size of the MNPs below 10 nm leads to the formation of necklace like [small beta]-Ga2O3 NWs via the encapsulation of the MNPs which act as catalytic centres for the formation of branched nanostructures along the length of the [small beta]-Ga2O3 NWs that are also responsible for a blue shift in the PL at 2.8 eV as a result of quantum confinement. This was not observed upon reducing the density of MNPs or in the case of ZnO or SnO2 NWs grown with the smallest of MNPs probably due to differences in surface energy. We show that polymethacrylate-noble MNPs may be patterned directly by electron beam lithography and may be exploited for the selective location growth of semiconductor NWs while we also discuss the difference between the sizes of the hybrid polymer-MNPs and MO NWs which is attributed to agglomeration.
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